Ah ha. I found the site that has the POP3 and SMTP's I need:

http://forum.theispguide.com/ftopic351-0-asc-15.html

And some of the people are saying this for hotmail:

POP3 = pop3hot.com
SMTP = mx1.hotmail.com

or

pop3: mail.pop3hot.com
smtp: mail.pop3hot.com

And so far it's working. It's downloading the mail from hotmail right now. Just gotta test something in VB after I get my contacts up.