Try this code. It will also delete the unwanted image as required in your comments:
vb.net Code:
  1. Private Sub Button1_Click(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles Button1.Click
  2.     Dim xlApp As Excel.Application
  3.     Dim xlWorkBook As Excel.Workbook
  4.     Dim xlWorkSheet As Excel.Worksheet
  5.     Dim olobj As Excel.Shape
  6.     Dim xlCharts As Excel.ChartObjects
  7.     Dim myChart As Excel.ChartObject
  8.     Dim I As Long = 1
  9.  
  10.     xlApp = New Excel.ApplicationClass
  11.     xlWorkBook = xlApp.Workbooks.Open("C:\Temp\Test.xlsx")
  12.     xlWorkSheet = xlWorkBook.Worksheets("Sheet1")
  13.     xlCharts = xlWorkSheet.ChartObjects
  14.     'myChart = xlCharts.Add(10, 80, 300, 250)
  15.  
  16.     '<~~ There could be more pictures than one
  17.     For Each olobj In xlWorkSheet.Shapes
  18.         myChart = xlCharts.Add(10, 80, 300, 250)
  19.         olobj.Copy()
  20.         myChart.Activate()
  21.         myChart.Chart.Paste()
  22.         myChart.Chart.Export("C:\Temp\Image" & I & ".gif", "GIF", True)
  23.         I = I + 1
  24.         myChart.Delete()
  25.     Next
  26.     xlWorkBook.Close(SaveChanges:=False)
  27.     xlApp.Quit()
  28.  
  29.     releaseObject(xlApp)
  30.     releaseObject(xlWorkBook)
  31.     releaseObject(xlWorkSheet)
  32. End Sub