First of all, I can't take full credit for this, as I borrowed this myself from somewhere, but can't remember where now.
Anywho, I've noticed quite a many request in this and other forums to figure out how to round corners of an object.
So i'm posting an Official Function that makes it very Easy.
Simply Copy & Paste the following function into your form somewhere
Round It Code:
  1. Private Sub makeRound(ByVal vObject As Object)
  2.         Dim p As New Drawing2D.GraphicsPath()
  3.         p.StartFigure()
  4.         p.AddArc(New Rectangle(0, 0, 20, 20), 180, 90)
  5.         p.AddLine(20, 0, vObject.Width - 20, 0)
  6.         p.AddArc(New Rectangle(vObject.Width - 20, 0, 20, 20), -90, 90)
  7.         p.AddLine(vObject.Width, 20, vObject.Width, vObject.Height - 20)
  8.         p.AddArc(New Rectangle(vObject.Width - 20, vObject.Height - 20, 20, 20), 0, 90)
  9.         p.AddLine(vObject.Width - 20, vObject.Height, 20, vObject.Height)
  10.         p.AddArc(New Rectangle(0, vObject.Height - 20, 20, 20), 90, 90)
  11.         p.CloseFigure()
  12.  
  13.         vObject.Region = New Region(p)
  14.     End Sub

For more of a rounded curve try replacing all of the "20"s with "40"
To make use on almost any object in a form simply:
Use It Code:
  1. makeRound(yourObject)
  2. '    Like
  3. makeRound(TreeView1)

Tada!