Alright, I did a search on vb forums and found something that helped me out:

vb Code:
  1. Dim itmX As ListViewItem = lstStudents.FindItemWithText(tstSearch.Text, False, 0)

  2.         If Not itmX Is Nothing Then

  3.             lstStudents.Focus()

  4.             itmX.Selected = True

  5.             lstStudents.Items(itmX.Index).Selected = True

  6.             itmX.EnsureVisible()

  7.         End If

So here's the problem know. When have more than 1 of the same text (say, Last Name or First Name) Then it will only do the very last item, instead of starting with the FIRST item & then when I click the search Button again, it will go to the next item in the List with that Text.