You can create a color by using the FromARGB method of the color structure.
This would create a color with red, green, and blue values of 255, which is of course white.
Code:
Dim WhiteColor As Color = Color.FromArgb(255, 255, 255)
So you could basically just grab 3 random numbers between the values of 0 (black) and 255 (white) and use those random values to create a random color.
Also, your signature is way too big, please adjust the fonts.