Good VB.Net self-learning book for first-time programming student

I need to teach someone VB.Net (2010 if that matters.)

A little description about my student:
My student is an intelligent young man but very new to "computer thingies".
He is not a power user, doesn't know anything about core computer science.

He wants to learn programming just as a hobby.
But, I think, if he gets interested in this, probably I'll be able to convince him to take CS as major. :)
My target is to make him efficient enough so that he will be able to impress his friends (and probably GF too) showing his own little desktop apps within 2-3 months.
In next step I'll start web programming.

I'm looking for a TEACH-YOURSELF type book which is written in clear language and good explanation.
Obviously I'll help him if he gets stuck, but I don't want to (and don't have time to) babysit him.

I have absolutely no idea about beginner level books. So, please help me on this.

In addition if you can suggest for good "how-computer-works" or "fundamental-of-computers" type books, that would be a great help too.

Thanks.
:)

I refer every new person to home and learn. It's online and free, and free is my second favorite 4-letter f word. I started programming in 2011 and home and learn was number one source of learning.

Darn Louisianans and their love of frog.

:O he knew!

It's that cajun influence.

With out a doubt wrox.com you cant go wrong. Great simple layout, easy to use and quite often you can get emails back from the authors.

Beginning Visual Basic 2012 is a great beginners book.

I also cant say enough for reference books to go along side a tutorial book. Aimed at all levels and teaches lots of little tricks and tips.

Visual Basic 2012 Programmer's Reference