VS 2010 Beginner: Need suggestion for organizing values

Hello! I am having an issue with picking which method to use for storing values. Thanks in advance for helping!

I have values of multiple types (Integer, Boolean, String) that I would like to sort into a table-like structure for ease of access. I've looked into several methods, but I would like some advice from experienced programmers to help me make an informed decision. By table-like, I mean in a sense that the data can be sorted into a rows and columns structure. The data being sorted will be static, so non-dynamic storage isn't a deal breaker.

I hope to be able to do something like this:
storage(row 1, column 1) = john
storage(row 1, column 2) = doe
storage(row 2, column 1) = jane
storage(row 2, column 2) = doe
stringvalue = storage(row 1, column 2)

From what I've looked at, it appears either arrays or a database is the way to go, but I'd really like some advice before proceeding.

Thanks for reading, any advice is appreciated!