ListView.AllowColumnReorder

I have been asked to simulate the way Excel allows you to "Freeze" certain columns so that when you scroll they are still visible. I thought I could do this by reordering the columns when the scroll bar is clicked. I know that you can allow the user to resort by switching the ListView.AllowColumnReorder flag to True but can I manually switch columns through code? Does anyone have another suggestion for this functionality? Keep in mind that there will be a large number of rows for the ListView.